1. Which one of the following is most abundant in the earth crust?
(a) Aluminium is the most abundant metal in the Earth's crust. 2. Melting point is highest for
(a) Boron (B) has the highest melting point among the given options. 3. Which of the following is the smallest cation?
(d) Al3+ has the smallest size due to higher charge and greater effective nuclear charge. 4. Which of the following minerals does not contain Al?
- Cryolite
- Mica
- Feldspar
- Fluorspar
(d) Fluorspar (CaF2) does not contain aluminium. 5. The chief ore of aluminium is
- Alunite
- Bauxite
- Cryolite
- Felspar
(b) Bauxite (Al2O3.2H2O) is the primary ore of aluminium. 6. The chemical composition of cryolite mineral is
- Al2O3
- Al2O3.12H2O
- KAlS3O8
- Na3AlF6
7. Corundum is an ore of
(c) Corundum (Al2O3) is an ore of aluminium. 8. Aluminium is extracted by the electrolysis of
- Bauxite
- Alumina
- Alumina mixed with molten cryolite
- Molten cryolite
(c) Alumina (Al2O3) dissolved in molten cryolite is used for extraction. 9. A layer of coke is spread over bauxite during extraction of aluminium. This acts as a/an
- Flux
- Slag to remove impurities
- Reducing agent
- Insulation and does not allow heat to escape
(d) Coke acts as an insulating layer to prevent heat loss. 10. In the extraction of aluminium the electrolyte is
- Fused cryolite with felspar
- Fused cryolite with fluorspar
- Pure alumina in molten cryolite
- Pure alumina with bauxite and molten cryolite
(c) The electrolyte is Al2O3 dissolved in molten cryolite. 11. Aluminium is obtained by
- Reducing Al2O3 with coke
- Electrolysing Al2O3, dissolved in Na3AlF6
- Reducing Al2O3 with chromium
- Heating alumina and cryolite
(b) Aluminium is obtained by electrolysis of Al2O3 in Na3AlF6. 12. In the electrolysis of alumina, cryolite is added to
- Increase the melting point of alumina
- Increase the electrical conductivity
- Minimise the anodic effect
- Remove impurities from alumina
(b) Cryolite increases conductivity and lowers melting point. 13. Electrolytic reduction of alumina to aluminium by Hall-Heroult process is carried out
- In the presence of NaCl
- In the presence of fluorite
- In the presence of cryolite which forms a melt with lower melting temperature
- In the presence of cryolite which forms a melt with high melting temperature
(c) Cryolite lowers the melting point of alumina. 14. The function of fluorspar in the electrolytic reduction of alumina dissolved in fused cryolite (Na3AlF6) is
- As a catalyst
- To lower the temperature of the melt and to make the fused mixture very conducting
- To decrease the rate of oxidation of carbon at the anode
- None of the above
(b) Fluorspar (CaF2) improves conductivity and lowers melting point. 15. Which metal is extracted only by electrolytic reduction?
(a) Aluminium is too reactive to be reduced by chemical methods. 16. Aluminium metal is refined by[IOM]
- Serpeck's process
- Baeyer's process
- Hoop's process
- Hall's process
(c) Hoop's process is used for refining aluminium. 17. Aluminium becomes passive in
- Conc. HNO3
- H2CrO4
- HClO4
- All of these
(d) Al forms a protective oxide layer in these oxidising agents. 18. Which metal is protected by a layer of its own oxide?
(a) Al forms Al2O3, which prevents further corrosion. 19. Aluminium is more reactive than iron. But aluminium is less easily corroded than iron because
- Aluminium is a noble metal
- Oxygen forms a protective oxide layer
- Iron undergoes reaction easily with water
- Iron forms mono and divalent ions
(b) Al2O3 layer protects aluminium from further corrosion. 20. Aluminium vessels should not be washed with materials containing washing soda since
- Washing soda is expensive
- Washing soda is easily decomposed
- Washing soda reacts with aluminium to form soluble aluminate
- Washing soda reacts with aluminium to form insoluble aluminium oxide
(c) NaOH (in washing soda) reacts with Al to form soluble NaAlO2. 21. Which of the following process does not involve a catalyst?
- Haber's process
- Thermite process
- Contact process
- Ostwald process
(b) Thermite process (Al + Fe2O3) does not require a catalyst. 22. Thermite is a mixture of
- 3 parts of powdered Al and 1 part of Fe2O3
- 1 part of powdered Al and 3 parts of Fe2O3
- 1 part of powdered Al and 1 part of Fe2O3
- 2 parts of powdered Al and 1 part of Fe2O3
(a) Thermite mixture is 3:1 (Al:Fe2O3). 23. In thermite process which of the following is used as a reducing agent?[IOM, MOE]
(a) Aluminium reduces Fe2O3 to Fe. 24. In thermite welding process we use
- Al powder
- Fe powder
- Ca powder
- Al + Fe mixture
(d) Thermite welding uses a mixture of Al and Fe2O3. 25. Which of the following bases will react with alkalies?
(d) Al2O3 is amphoteric and reacts with NaOH. 26. Aluminium oxide is not reduced by chemical reactions since
- Aluminium oxide is highly stable
- Aluminium oxide is reactive
- Reducing agents contaminate
- The process pollutes the environment
(a) Al2O3 has very high stability due to strong Al-O bonds. 27. Substance soluble in NaOH is
- Ba(OH)2
- Cu(OH)2
- Fe(OH)2
- Al(OH)3
(d) Al(OH)3 dissolves in NaOH to form NaAlO2. 28. Anhydrous AlCl3 fumes in moist air because of
- Dehydration
- Hydrolysis
- Hydration
- Oxidation
(b) AlCl3 hydrolyzes in moisture to form HCl fumes. 29. Aluminium (III) chloride forms a dimer because
- Aluminium has high ionization energy
- It cannot form a trimer
- Higher coordination number can be achieved by aluminium
- Aluminium belongs to third group
(c) Al achieves coordination number 6 by forming Al2Cl6. 30. Common alum is
- K2SO4.Al2(SO4)3.24H2O
- K2SO4.Cr2(SO4)3.24H2O
- K2SO4.Fe2(SO4)3.24H2O
- (NH4)2SO4.FeSO4.6H2O
(a) Common alum is K2SO4.Al2(SO4)3.24H2O. 31. Which of the following does not form alum?
(a) Lithium (Li+) does not form alum due to small size. 32. Aqueous solution of potash alum is
- Acidic
- Alkaline
- Neutral
- Not definite
(a) Due to hydrolysis of Al3+, the solution is acidic. 33. Potash alum is water soluble and ionises in aqueous solution to give
- Only one type of ion
- Two types of ions
- Three types of ions
- Four types of ions
(d) K+, Al3+, SO42-, and H2O. 34. The important source of boron is
- Calamine
- Carnalite
- Colemanite
- Cryolite
(c) Colemanite (Ca2B6O11.5H2O) is a source of boron. 35. H3BO3 is
- Monobasic and weak Lewis acid
- Monobasic and weak Bronsted acid
- Monobasic and strong Lewis acid
- Tribasic and weak Bronsted acid
(a) H3BO3 accepts OH- (Lewis acid) and is monobasic. 36. Which one of the following is not an electron deficient compound?
(c) Al2Cl6 is not electron-deficient due to dimerization. 37. Three centred bond is present in
(b) B2H6 has 3c-2e (banana) bonds. 38. The hardest compound of boron is
- Boron carbide
- Boron nitride
- Silicon boride
- Magnesium boride
(a) Boron carbide (B4C) is extremely hard. 39. Borazole is known as
- Organic benzene
- Organic compound
- Inorganic benzene
- Inorganic compound
(c) Borazole (B3N3H6) is called inorganic benzene. 40. Chemically borax is
- Sodium metaborate
- Sodium orthoborate
- Sodium tetraborate
- Sodium tetraborate decahydrate
(d) Borax is Na2B4O7.10H2O. 41. Borax is prepared by treating colemanite with
(c) Colemanite reacts with Na2CO3 to form borax. 42. In the borax bead test of Co2+, the blue colour of bead is due to the formation of
(b) Co(BO2)2 gives a blue bead. 43. Borax bead test is not given by
- Cobalt salts
- Copper salts
- Aluminium salts
- Nickel salts
(c) Aluminium does not give a characteristic borax bead test. 44. In diborane
- 4 bridged hydrogens and two terminal hydrogens are present
- 2 bridged hydrogens and four terminal hydrogens are present
- 3 bridged and three terminal hydrogens are present
- None of the above
(a) B2H6 has 4 bridging and 2 terminal H atoms. 45. In diborane, banana bond is formed between
- 2 electrons, 3 atoms
- 2 electrons, 1 atom
- 2 electrons, 2 atom
- 1 electron, 2 atoms
(a) 3c-2e (banana) bond involves 2 electrons shared by 3 atoms. 46. Which one is a Lewis acid?
(b) AlCl3 has an incomplete octet and acts as a Lewis acid. 47. Which of the following is the strongest Lewis acid?
(a) BI3 is the strongest due to poor backbonding. 48. Aluminium is most abundant in earth crust, yet it is obtained from bauxite because
- Bauxite is available in large quantity
- Of easy extraction of aluminium from it
- Bauxite contains maximum aluminium
- Bauxite is less impure
(b) Bauxite is the most economically viable source for extraction. 49. Anhydrous AlCl3 is prepared from
- Conc. HCl and aluminium metal
- Aluminium and Cl2
- Dry HCl gas + heated aluminium metal
- Dil. HCl and aluminium metal
(b) Al + Cl2 → AlCl3 (anhydrous). 50. The process of converting hydrated alumina into anhydrous alumina is called
- Roasting
- Smelting
- Dressing
- Calcination
(d) Calcination removes water from hydrated alumina.