1. Sodium is commercially obtained by the electrolysis of its fused sodium chloride. The process is called[IOM]
- Castner process
- Down's process
- Solvay process
- Kellner process
(b) Down's process uses electrolysis of molten NaCl/CaCl2 mixture to produce sodium 2. Which of the following metals gives golden yellow colour on flame test[IOM]
(d) Sodium gives characteristic golden yellow flame (589 nm) 3. Borax is
- Na2B4O7.10H2O
- Na3BO3.4H2O
- Na2B4O4.7H2O
- Na2B4O7.5H2O
(a) Borax formula: Na2B4O7.10H2O (sodium tetraborate decahydrate) 4. What happens when ZnCl2 is treated with NaOH[IOM]
- Black ppt. is formed
- No ppt. is formed
- White ppt. is formed which is soluble in excess of NaOH
- White ppt. is formed which is insoluble in excess of NaOH
(c) Zn2+ + 2OH- → Zn(OH)2 (white) → [Zn(OH)4]2- in excess NaOH 5. Sodium reacts more vigorously with water than lithium because sodium is
- Heavier than lithium
- More electropositive than lithium
- Less electropositive than lithium
- A non metal
(b) Higher electropositivity means greater tendency to lose electrons 6. Alkali metals are good reducing agents because[IOM]
- They are metal
- They are monovalent
- Their ionization potential is low
- They have small atomic radii
(c) Low ionization energy means electrons are easily lost (strong reduction) 7. When conc. solution of NaCl in water is saturated with NH3 and then CO2 is passed through the liquid NaCl is converted into
(b) Solvay process: NaCl + NH3 + CO2 + H2O → NaHCO3 + NH4Cl 8. The electronic configuration of an element is 2, 8, 1. Which of the following statement is true?
- It is diatomic
- It is a non metal
- It is a transitional metal
- It forms basic oxide
(d) Configuration indicates sodium (Na) which forms Na2O (basic oxide) 9. Metallic lustre of sodium metal can be explained on the basic of
- Diffusion of sodium ions
- Oscillation of loose electrons
- Existence of free protons
- Existence of body centred lattice
(b) Metallic lustre due to interaction of light with free electrons 10. A solution of sodium metal in liquid ammonia is strongly reducing due to the presence of[BPKIHS]
- Sodium atoms
- Sodium hydride
- Sodium amide
- Solvated electrons
(d) Blue color due to solvated electrons (e-(NH3)x) which are strong reductants 11. Sodium and potassium are kept under[BPKIHS]
- Alcohol
- Water
- Kerosene
- Aqua regia
(c) Stored under kerosene to prevent reaction with air/moisture 12. Fire extinguisher contains H2SO4 and[BPKIHS]
- NaHCO3+Na2CO3
- Na2CO3
- NaHCO3 solution
- CaCO3
(c) Acid + NaHCO3 produces CO2 which smothers fire 13. Electrolytic reduction method is used in the extraction of[BPKIHS]
- Highly electropositive element
- Highly electronegative element
- Inert metals
- Transitional metals
(a) Highly electropositive metals (Na, K, Ca, Al) require electrolysis 14. The best material used in photo emission is[IOM 1992]
(c) Cesium has lowest work function (easiest electron emission) 15. Excess of NaOH when reacts with zinc produces[IOM 1992]
- NaOH + ZnO
- ZnH
- Na2ZnO2+H2
- Zn(OH)2
(c) Zn + 2NaOH → Na2ZnO2 (sodium zincate) + H2 16. The chemicals that are consumed during the manufacture of sodium carbonate by Solvay's process are[MOE 2066]
- Calcium carbonate and sodium chloride
- Calcium hydroxide as ammonia
- Ammonium bicarbonate and sodium chloride
- Calcium chloride and sodium chloride
(a) Main reactants: NaCl + CaCO3 → Na2CO3 + CaCl2 17. In the manufacture of washing soda Na2CO3 the compound formed after the treatment of ammonical brine solution with CO2 is[MOE 2008]
- Na2CO3
- NaHCO3
- (NH4)2CO3
- None
(b) First product is sodium bicarbonate (NaHCO3) which is then heated to make Na2CO3 18. Sodium is made by electrolysis of molten mixture of about 40% NaCl and 60% CaCl2 because[MOE 2008]
- CaCl2 helps in conduction of electricity
- This mixture has lower melting point of NaCl solution
- Ca++ can displace Na+ from NaCl
- Ca++ can reduce NaCl to Na
(b) CaCl2 lowers melting point from 801°C (pure NaCl) to ~600°C 19. Caustic soda can be manufactured by[MOE 2063]
- Solvay - ammonia soda process
- Castner - kellner process
- Down's process
- Cyanide process
(b) Castner-Kellner cell: electrolysis of brine using mercury cathode 20. How many water of crystallization (WOC) is present in a molecule of washing soda?[MOE 2062]
(b) Washing soda: Na2CO3.10H2O 21. In Down's process for the extraction of sodium[MOE 2061]
- C is anode and Fe is cathode
- C is cathode and Fe is anode
- Pt is anode and Fe is cathode
- C is anode and Pt is cathode
(a) Graphite anode and iron cathode in molten NaCl/CaCl2 22. The alkali metals can easily be detected by the flame test, because they have[MOE 2050]
- Low ionization energy
- Low density
- Low electron affinity
- High conductance
(a) Easy excitation of outer electrons due to low ionization energy 23. The hydride of an element E reacts with water producing hydrogen and an alkali solution. The element 'E' is probably[MOE 2050]
- An alkali metal
- A transitional metal
- A metal low in activity series
- A metal in group IV
(a) NaH + H2O → NaOH + H2 (typical alkali metal hydride reaction) 24. Which of the following elements exists in only one oxidation state in most of its compound?[Bangladesh 2066]
(b) Potassium almost always shows +1 oxidation state 25. Sodium nitrate decomposes above 800°C to give
(d) 2NaNO3 → 2NaNO2 + O2 (but at very high temp: 2NaNO3 → Na2O + N2 + 2.5O2) 26. NaOH is manufactured by the electrolysis of brine solution. The products of reaction are[MOE]
- Cl2 and H2
- Cl2 and Na-Hg
- Cl2 and Na
- Cl2 and O2
(a) 2NaCl + 2H2O → 2NaOH + Cl2 + H2 (Chlor-alkali process) 27. Squashes are stored by adding
- Citric acid
- KCl
- Na2SO3
- Sodium metabisulphite (Na2S2O5)
(d) Na2S2O5 acts as preservative (releases SO2) - Na2CO3.H2O
- Na2CO3
- NaOH
- NaHCO3
(b) Soda ash = anhydrous sodium carbonate 29. What is the product formed when CO2 is bubbled into aqueous solution of Na2CO3[KU]
(b) Na2CO3 + CO2 + H2O → 2NaHCO3 30. Which of the following are recycled in the manufacture of Na2CO3[IOM]
- CO2 and NH3
- CO2 and NH4Cl
- NaCl and CaO
- CaCl2 and CaO
(a) In Solvay process, NH3 is recovered from NH4Cl and CO2 is reused