1. The size of particles in suspension, true solution and colloidal solution varies in the order
- Suspension > Colloidal > True Solution
- True Solution > Suspension > Colloidal
- Suspension > Colloidal = True Solution
- None of the above
(a) Suspension (>1000 nm) > Colloidal (1-1000 nm) > True Solution (<1 nm) 2. A colloidal system has particles of what size?
- 10-7 m to 10-5 m
- 10-9 m to 10-7 m
- 10-9 m to 10-6 m
- 10-7 m to 10-9 m
(d) Colloidal particles range from 1-1000 nm (10-9 to 10-7 m) 3. Cloud or fog is an example of colloidal system of
- Liquid dispersed in gas
- Gas dispersed in gas
- Solid dispersed in gas
- Solid dispersed in liquid
(a) Cloud/fog are liquid (water droplets) dispersed in gas (air) 4. Milk is
- Fat dispersed in milk
- Fat dispersed in water
- Water dispersed in fat
- Water dispersed in oil
(b) Milk is fat globules dispersed in aqueous medium (oil-in-water emulsion) 5. Smoke is an example of
- Gas dispersed in liquid
- Gas dispersed in solid
- Solid dispersed in gas
- Solid dispersed in solid
(c) Smoke consists solid particles dispersed in gas (air) 6. Butter is a colloid formed when
- Fat is dispersed in water
- Fat globules are dispersed in water
- Water is dispersed in fat
- None of the above
(c) Butter is water-in-fat emulsion (reverse of milk) 7. Butter is
- A gel
- An emulsion
- A sol
- None of these
(b) Butter is an emulsion (water droplets in fat matrix) 8. The extra stability of lyophilic colloids is due to
- Charge on their particles
- A layer of medium of dispersion on their particles
- The smaller size of their particles
- The larger size of their particles
(b) Solvation layer provides stability to lyophilic colloids 9. Flocculation value is expressed in terms of
- millimole L-1
- mole L-1
- gram L-1
- mole mL-1
(a) Flocculation value = millimoles of electrolyte per liter required to cause precipitation 10. Light scattering takes place in
- solutions of electrolyte
- colloidal solutions
- electrodialysis
- electroplating
(b) Tyndall effect (light scattering) is characteristic of colloids 11. Minimum quantity of electrolyte which can precipitate any colloid is
- Gold number
- Avogadro number
- Flocculation value
- Peptisation value
(c) Flocculation value measures precipitation power of electrolytes 12. The coagulation power of an electrolyte for As2S3 decreases in the order
- Na+, Al3+, Ba2+
- Cl-, SO42-, PO43-
- Al3+, Ba2+, Na+
- PO43-, SO42-, Cl-
(d) As2S3 is negative sol, so anion effectiveness follows Hardy-Schulze rule (higher charge more effective) 13. The charge on As2S3 sol is due to the adsorbed
(d) As2S3 adsorbs S2- ions giving negative charge 14. The migration of colloidal particles under the influence of an electric field is known as
- electro-osmosis
- brownian movement
- cataphoresis
- dialysis
(c) Cataphoresis = electrophoresis (movement of charged particles in electric field) 15. The sky looks blue due to
- Dispersion effect
- Reflection
- Transmission
- Scattering
(d) Rayleigh scattering of sunlight by atmospheric particles (shorter λ like blue scattered more) 16. Which one of the sols acts as protective colloid?
(b) Gelatin is a lyophilic colloid that protects lyophobic colloids from precipitation 17. Gold number represents
- quantity of gold in alloys
- percentage of gold in gold biscuits
- colloid protective power
- percentage quantity of gold in colloidal gold
(c) Gold number measures protective colloid efficiency (lower value = better protection) 18. What is gold number?
- It is the weight in mg of the dry material which when added to 10 c.c. of red gold will prevent coagulation on adding 1 c.c. of 10% NaCl
- It is the weight in mg of the dry material which when added to 1 c.c. of red gold sol will prevent coagulation on adding 10 c.c. of 10% NaCl
- It is the weight in mg of the dry material which when added to 1 c.c. of red gold sol will prevent coagulation on adding 1 c.c. of 1% NaCl
- None of the above
(c) Gold number: mg of protective colloid needed to prevent 1 mL gold sol from coagulating with 1 mL 10% NaCl 19. Gold number is minimum in case of
- Gelatin
- Egg albumin
- Gum arabic
- Starch
(a) Gelatin has lowest gold number (0.005-0.01) → most effective protective colloid 20. According to Langmuir adsorption isotherm, the amount of gas adsorbed at very high pressures
- reaches a constant limiting value
- goes on increasing with pressure
- goes on decreasing with pressure
- increases first and decreases later with pressure
(a) At high pressure, monolayer coverage completes → adsorption reaches saturation 21. Which colloid is used in treating eye disease?
- Colloidal S
- Colloidal antimony
- Colloidal gold
- Colloidal silver
(d) Colloidal silver (argyrol) used as eye antiseptic 22. As2S3 sol is
- positive colloid
- negative colloid
- neutral colloid
- none of the above
(b) As2S3 adsorbs S2- ions → negative sol 23. Small liquid droplets dispersed in another liquid is
- suspension
- emulsion
- gel
- true solution
(b) Emulsion = liquid-liquid colloidal system 24. Alum helps in purifying water due to
- forming Si complex with clay particles
- sulphate part which combines with the dirt and removes it
- aluminium which coagulates the mud particles
- making mud water soluble
(c) Al3+ ions neutralize negative charges on suspended particles → coagulation 25. In physical adsorption, the force associated are
- ionic
- covalent
- van der Waal's
- hydrogen bonding
(c) Physisorption involves weak van der Waals forces 26. Adsorption due to strong chemical forces is called
- chemisorption
- physisorption
- reversible adsorption
- both b & c
(a) Chemisorption involves chemical bond formation 27. A catalyst increases the rate of reaction because it
- increases the activation energy
- decreases the energy barrier for reaction
- decreases the collision diameter
- increases the temperature coefficient
(b) Catalysts provide alternative pathway with lower activation energy 28. Which is not a characteristic of a catalyst?
- It changes the equilibrium constant
- It alters the reaction path
- It increases the rate of reaction
- It does not affect the average K.E. of the molecules
(a) Catalysts don't change equilibrium position (affect both forward/reverse rates equally) 29. In the reversible reaction a catalyst is the substance which
- increases the rate of the forward reaction
- decreases the value of enthalpy change in the reaction
- reduces the time required for reaching the equilibrium state
- decreases the rate of the reverse reaction
(c) Catalyst speeds up both forward/reverse reactions → reaches equilibrium faster 30. In the hydrogenation of oils the catalyst used is
- Iron
- Platinum
- Nickel
- Molybdenum
(c) Finely divided Ni used in hydrogenation of vegetable oils 31. In which of the following commercial processes a catalyst is not used?
- Haber's process
- Deacon's process
- Solvay process
- Lead chamber process
(c) Solvay process (Na2CO3 production) doesn't use catalyst 32. In the case of auto-catalysis
- reactant catalyses
- product catalyses
- solvent catalyses
- heat produced in the reaction catalyses
(b) Auto-catalysis: product acts as catalyst (e.g., KMnO4 + oxalic acid) 33. The enzyme which can catalyse the conversion of glucose to ethanol is
- Zymase
- Invertase
- Maltase
- Diastase
(a) Zymase (in yeast) converts glucose → ethanol + CO2 34. Rusting of iron is catalyzed by which of the following?
(d) Water acts as catalyst in rusting (4Fe + 3O2 → 2Fe2O3) 35. In the Ostwald's process for the manufacture of HNO3, the catalyst used is
(d) Pt-Rh gauze catalyzes NH3 → NO oxidation 36. A catalyst
- increases the average kinetic energy of molecules
- increases the activation energy
- decreases the activation energy
- increases the frequency of collisions of reacting species
(c) Catalyst works by lowering activation energy barrier 37. Which of the following will be most effective in the coagulation of Fe(OH)3 sol?
(d) Fe(OH)3 is positive sol → PO43- most effective (Hardy-Schulze rule) 38. Tyndall effect in colloidal solutions is due to
- scattering of light by the particles
- reflection of light by the particles
- movement of particles
- coagulation of particles
(a) Tyndall effect = scattering of light by colloidal particles 39. Blood cells do not shrink in blood because blood is
- hypotonic
- isotonic
- equimolar
- hypertonic
(b) Isotonic solution maintains cell volume (no net water movement) 40. An example of dispersion of a liquid in a gas is
- vegetable oil
- milk
- foam
- mist
(d) Mist = liquid droplets (water) in gas (air) 41. Which of the following is not represented by sols
- Adsorption
- Tyndall effect
- Flocculation
- Paramagnetism
(d) Paramagnetism is atomic/molecular property unrelated to colloidal state 42. Tyndall effect is exhibited by
- NaCl solution
- Starch solution
- Urea solution
- FeCl3 solution
(b) Starch forms colloidal solution showing Tyndall effect 43. Surface tension of lyophilic solution is
- Lower than water
- More than water
- Equal to water
- None
(a) Lyophilic colloids reduce surface tension of medium 44. Adsorption is multilayer in case of
- Physical adsorption
- Chemisorption
- Both
- None
(a) Physisorption can form multilayers, chemisorption only monolayer 45. Which of the following term is negative in adsorption?
- ΔH
- ΔS
- Both a and b
- ΔS is -ve and ΔH is +ve
(b) Adsorption decreases randomness → negative ΔS 46. Which of the following is adsorbate?
- Silica gel
- Charcoal powder
- Wood
- Ammonia
(d) Adsorbate = substance being adsorbed (NH3 on charcoal) 47. The decomposition of H2O2 can be slowed by the addition of a small amount of acetamide. The later acts as
- Detainer
- Stopper
- Promoter
- Inhibitor
(d) Acetamide inhibits H2O2 decomposition